Single‐run capillary electrophoresis method for the fast simultaneous determination of amoxicillin,clavulanate, and potassium

We report a new fast method for the simultaneous determination of amoxicillin, clavulanate, and potassium by capillary electrophoresis with capacitively coupled contactless conductivity detection. Samples containing potassium as the cation, and both amoxicillin and clavulanate as anions were determined simultaneously in a single run (in less than 45 s) using 10 mmol/L of both 2‐amino‐2‐hydroxymethyl‐propane‐1,3‐diol and 3‐{[2‐hydroxy‐1,1‐bis(hydroxymethyl)ethyl]amino}‐1‐propanesulfonic acid (pH 8.4) as the background electrolyte. Limits of detection were 25.0, 5.0, and 4.0 μmol/L for amoxicillin, clavulanate, and potassium, respectively. The proposed method is inexpensive, simple, fast (75 injections h⁻¹), environment friendly (minimal waste generation), and accurate (recovery values between 98 and 103%). The results obtained with the proposed method were statistically similar (95% confidence level) to those obtained by using high‐performance liquid chromatography (amoxicillin and clavulanate) and flame photometry (potassium).     

Ab initio multi-reference configuration interaction of the low-lying states of the AsP molecule

Nine low-lying electronic states of the AsP molecule, including Σ , Ⅱ, and △ symmetries with singlet, triplet, and quintet spin multiplicities, are studied using multi-reference configuration interaction method.The potential energy curves and the spectroscopic constants of these nine states are determined, and compared with the experimental observed data as well as other theoretical works available at present.Three quintet states are reported for the first time.Furthermore, the analytical potential energy functions of these states are fitted using Murrell-Sorbie function and least square fitting method.     

虚拟仪器技术及乐音的频谱分析

阐述了虚拟仪器技术的概念和特点,精确测量了３ 种乐音信号的波形、频谱和频率     

HAMILTONIAN SYSTEM AND SIMPLETIC GEOMETRY IN MECHANICS OF COMPOSITE MATERIALS (Ⅱ)——PLANE STRESS PROBLEM

Fundamental theory presented in Part (I)^[8] is used to analyze anisotropic plane stress problems. First we construct the generalized variational principle to enter Hamiltonian system and get Hamiltonian differential operator matrix; then we solve eigen problem; finally, we present the process of obtaining analytical solutions and semi-analytical solutions for anisotropic plane stress problems on rectangular area.     

Mathematical modeling of a steam generator for sensor fault detection

A dynamic model for a nuclear power plant steam generator (vertical, preheated, U-tube recirculation-type) is formulated as a sixth-order nonlinear system. The model integrates nodal mass and energy balances for the primary water, the U-tube metal and the secondary water and steam. The downcomer flow is determined by a static balance of momentum. The mathematical system is solved using transient input data from the Philippsburg 2 (FRG) nuclear power plant. The results of the calculation are compared with actual measured values. The proposed model provides a low-cost tool for the automatic control and simulation of the steam generating process. The “parity-space” algorithm is used to demonstrate the applicability of the mathematical model for sensor fault detection and identification purposes. This technique provides a powerful means of generating temporal analytic redundancy between sensor signals. It demonstrates good detection rates of sensor errors using relatively few steps of scanning time and allows the reconfiguration of faulty signals.     

Three-Dimensional Analytical Models for Virus Transport in Saturated Porous Media

Analytical models for virus transport in saturated, homogeneous porous media are developed. The models account for three-dimensional dispersion in a uniform flow field, and first-order inactivation of suspended and deposited viruses with different inactivation rate coefficients. Virus deposition onto solid particles is described by two different processes: nonequilibrium adsorption which is applicable to viruses behaving as solutes; and colloid filtration which is applicable to viruses behaving as colloids. The governing virus transport equations are solved analytically by employing Laplace/Fourier transform techniques. Instantaneous and continuous/periodic virus loadings from a point source are examined.     

新型塑料导线直径在线测量系统

本文提出了一种用线阵ＣＣＤ非接触实时测量塑料导线直径的仪器，它有如下特点：（１）采用了对被测目标所发出的烟雾不敏感的光学系统，提高了测量精度；（２）采用工作于脉冲方式的大功率近红外ＬＥＤ做照明光源，其寿命比采用白炽灯作为光源大为增长，同时缩小了体积并有利于抑制可见光的干扰；（３）对电信号采用了两级滤波、直流恢复、自适应阈值二值化等处理技术；（４）采用定标的方法来消除目标位置移动的影响，提高了测量精度，降低了加工装配精度要求。现场使用证明，它能长期可靠地工作，总的测量误差小于±０．０２ｍｍ。     

The integral mean diffusivity for particle-gas mass transfer calculations under thermal plasma conditions

Plasma Chemistry and Plasma Processing - A new integral mean diffusivity is proposed for the calculation of the mass transfer rate around a small particle immersed in a thermal plasma gas....